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HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL MICROBAND ELECTRODES - POTENTIAL STEP TRANSIENTS

Abstract:

The current transients induced by a potential step at a microband electrode located in a rectangular channel through which solution is pumped under laminar flow conditions are described by theory which accounts for convection axially through the flow cell and diffusion normal, and parallel, to the electrode surface. The hopscotch algorithm is used to predict numerically the form of the chronoamperometric transients as a function of the flow cell/electrode geometries and as a function of flow ...

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Publication status:
Published

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Publisher copy:
10.1021/j100055a037

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Journal:
JOURNAL OF PHYSICAL CHEMISTRY More from this journal
Volume:
98
Issue:
4
Pages:
1270-1275
Publication date:
1994-01-27
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
Language:
English
UUID:
uuid:0b208ea9-0b12-4be4-871c-76c34c12bb9b
Local pid:
pubs:44339
Source identifiers:
44339
Deposit date:
2012-12-19

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