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New quenched-in fluorite-type materials in the Bi2O 3-La2O3-PbO system: Synthesis and complex phase behaviour up to 750 °c

Abstract:

New quenched-in fluorite-type materials with composition (BiO 1.5)0.94-x(LaO1.5)0.06(PbO) x, x = 0.02, 0.03, 0.04 and 0.05, were synthesised by solid state reaction. The new materials undergo a number of phase transformations during heating between room temperature and 750 °C, as indicated by differential thermal analysis. Variable temperature X-ray diffraction performed on the material (BiO1.5)0.92(LaO1.5) 0.06(PbO)0.02 revealed that the quenched-in fcc fluorite-type material first undergoes...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Materials Research Bulletin More from this journal
Volume:
46
Issue:
4
Pages:
538-542
Publication date:
2011-04-01
DOI:
ISSN:
0025-5408
Language:
English
Keywords:
Pubs id:
pubs:302873
UUID:
uuid:0b1bc6e6-283d-47a8-8311-0f62bbdd32d4
Local pid:
pubs:302873
Source identifiers:
302873
Deposit date:
2013-11-17

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