Journal article icon

Journal article

Rhodium phosphine olefin complexes of the weakly coordinating anions [BAr4F](-) and [1-closo-CB11H6Br6](-). Kinetic versus thermodynamic factors in anion coordination and complex reactivity

Abstract:

Solution and solid-state structures for the pair of complexes Rh{P(Cyp 2)(η2-C5H7)}{η6- (C6H3(CF3)2)BAr3F} and Rh{P(Cyp2)(η2-C5H 7)}(I-closo-CB11H6Br6), which contain bound weakly coordinating anions, are reported. While thermochemical data show that enthalpically [I-closo-CB11H6Br 6]- binds less strongly with the metal fragment and it is the large entropy loss for the overall process of coordination of the [BAr 4F]- anion that results in the latter anion being thermodynamically more weakly c...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/om060975d

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS More from this journal
Volume:
26
Issue:
3
Pages:
463-465
Publication date:
2007-01-29
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Language:
English
Pubs id:
pubs:51701
UUID:
uuid:0af29248-91e6-4549-b7b4-b546fa45e7c8
Local pid:
pubs:51701
Source identifiers:
51701
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP