- Abstract:
-
The solid-state chelation of transition metal ions (Co(2+), Ni(2+), and Cu(2+)) from aqueous solutions into the lithium aluminum layered double hydroxide ([LiAl(2)(OH)(6)]Cl x 0.5H(2)O or LDH) which has been pre-intercalated with EDTA (ethylenediaminetetraacetate) ligand has been investigated. The intercalated metal cations form [M(edta)](2)(-) complexes between the LDH layers as indicated by elemental analysis, powder X-ray diffraction, and IR and UV-vis spectroscopies. If metal chloride or ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic0203926
-
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- Journal:
- Inorganic chemistry
- Volume:
- 42
- Issue:
- 6
- Pages:
- 1919-1927
- Publication date:
- 2003-03-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:0aea2ea2-c64b-419f-bcb7-c9fb3c8f6d1b
- Source identifiers:
-
51208
- Local pid:
- pubs:51208
- Language:
- English
- Copyright date:
- 2003
Journal article
Solid-state chelation of metal ions by ethylenediaminetetraacetate intercalated in a layered double hydroxide.
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