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Solid-state chelation of metal ions by ethylenediaminetetraacetate intercalated in a layered double hydroxide.

Abstract:

The solid-state chelation of transition metal ions (Co(2+), Ni(2+), and Cu(2+)) from aqueous solutions into the lithium aluminum layered double hydroxide ([LiAl(2)(OH)(6)]Cl x 0.5H(2)O or LDH) which has been pre-intercalated with EDTA (ethylenediaminetetraacetate) ligand has been investigated. The intercalated metal cations form [M(edta)](2)(-) complexes between the LDH layers as indicated by elemental analysis, powder X-ray diffraction, and IR and UV-vis spectroscopies. If metal chloride or ...

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Publication status:
Published

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Publisher copy:
10.1021/ic0203926

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
42
Issue:
6
Pages:
1919-1927
Publication date:
2003-03-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
51208
Language:
English
Pubs id:
pubs:51208
UUID:
uuid:0aea2ea2-c64b-419f-bcb7-c9fb3c8f6d1b
Local pid:
pubs:51208
Deposit date:
2012-12-19

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