Journal article
SCOPE OF THE CHROMIUM(II)-MEDIATED SYNTHESIS OF E-ALKENYLSTANNANES FROM ALDEHYDES AND BU(3)SNCHBR(2)
- Abstract:
- The synthesis of E-alkenylstannanes from aldehydes and a mixture of Bu3SnCHBr2, LiI and CrCl2 is described. A mechanism is proposed to account for the alkene geometry in chromium(II)-mediated alkene synthesis which involves stereoselective addition by a gem-dichromium reagent to an aldehyde followed by a stereospecific elimination step. © 1995.
- Publication status:
- Published
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- Publisher copy:
- 10.1016/0040-4020(95)00086-N
Authors
- Journal:
- TETRAHEDRON More from this journal
- Volume:
- 51
- Issue:
- 12
- Pages:
- 3713-3724
- Publication date:
- 1995-03-20
- DOI:
- ISSN:
-
0040-4020
- Language:
-
English
- Pubs id:
-
pubs:52141
- UUID:
-
uuid:0ac26224-8b57-450d-80af-c03036c235ae
- Local pid:
-
pubs:52141
- Source identifiers:
-
52141
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 1995
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