Journal article icon

Journal article

SCOPE OF THE CHROMIUM(II)-MEDIATED SYNTHESIS OF E-ALKENYLSTANNANES FROM ALDEHYDES AND BU(3)SNCHBR(2)

Abstract:
The synthesis of E-alkenylstannanes from aldehydes and a mixture of Bu3SnCHBr2, LiI and CrCl2 is described. A mechanism is proposed to account for the alkene geometry in chromium(II)-mediated alkene synthesis which involves stereoselective addition by a gem-dichromium reagent to an aldehyde followed by a stereospecific elimination step. © 1995.
Publication status:
Published

Actions


Access Document


Journal:
TETRAHEDRON More from this journal
Volume:
51
Issue:
12
Pages:
3713-3724
Publication date:
1995-03-20
DOI:
ISSN:
0040-4020
Language:
English
Pubs id:
pubs:52141
UUID:
uuid:0ac26224-8b57-450d-80af-c03036c235ae
Local pid:
pubs:52141
Source identifiers:
52141
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP