Journal article
Oxidation of several p-phenylenediamines in room temperature ionic liquids: Estimation of transport and electrode kinetic parameters
- Abstract:
-
The electrochemical oxidation of N,N,N′,N′-tetramethyl-p- phenylenediamine (TMPD) has been studied by cyclic voltammetry and potential step chronoamperometry at 303 K in five ionic liquids, namely [C 2mim][NTf2], [C4mim][NTf2], [C 4mpyrr][NTf2], [C4mim][BF4], and [C4mim][PF6] (where [Cnmim]+ = 1-alkyl-3-methylimidazolium, [C4mpyrr]+ = N-butyl-N-methylpyrrolidinium, [NTf2]- = bis(trifluoromethylsulfonyl)-imide, [BF4]- = tetrafluoroborate, and [PF6]- = hexafluorophosphate). Diffusion coefficien...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/jp800235t
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Authors
Bibliographic Details
- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY C
- Volume:
- 112
- Issue:
- 17
- Pages:
- 6993-7000
- Publication date:
- 2008-05-01
- DOI:
- EISSN:
-
1932-7455
- ISSN:
-
1932-7447
- Source identifiers:
-
40710
Item Description
- Language:
- English
- UUID:
-
uuid:0a9065c8-12c2-4700-96e2-f5d72a5d828d
- Local pid:
- pubs:40710
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2008
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