Journal article
CHIRAL RECOGNITION IN THE REACTION OF THE ENOLATE DERIVED FROM [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] WITH CIS-2,3-EPOXYBUTANE AND TRANS-2,3-EPOXYBUTANE - THE STEREOSELECTIVE SYNTHESIS OF CIS AND TRANS-BETA,GAMMA-DISUBSTITUTED-GAMMA-LACTONE
- Abstract:
- The reaction between the enolate derived from [(η5-C5H5)Fe(CO)(PPh3)CO CH2OCH2Ph] and cis- and trans-2,3-epoxybutane proceeds with a high degree of chiral recognition between the reagents (10:1) to give products which may be converted to β,γ-dimethyl-γ-lactones possessing trans- or cis- stereochemistry. © 1989.
- Publication status:
- Published
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- Publisher copy:
- 10.1016/S0040-4039(00)95262-6
Authors
- Journal:
- TETRAHEDRON LETTERS More from this journal
- Volume:
- 30
- Issue:
- 5
- Pages:
- 587-590
- Publication date:
- 1989-01-01
- DOI:
- ISSN:
-
0040-4039
- Language:
-
English
- Pubs id:
-
pubs:168597
- UUID:
-
uuid:0a655165-d9d7-4c9e-a858-e11faf788759
- Local pid:
-
pubs:168597
- Source identifiers:
-
168597
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 1989
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