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CHIRAL RECOGNITION IN THE REACTION OF THE ENOLATE DERIVED FROM [(ETA-5-C5H5)FE(CO)(PPH3)COCH2OCH2PH] WITH CIS-2,3-EPOXYBUTANE AND TRANS-2,3-EPOXYBUTANE - THE STEREOSELECTIVE SYNTHESIS OF CIS AND TRANS-BETA,GAMMA-DISUBSTITUTED-GAMMA-LACTONE

Abstract:
The reaction between the enolate derived from [(η5-C5H5)Fe(CO)(PPh3)CO CH2OCH2Ph] and cis- and trans-2,3-epoxybutane proceeds with a high degree of chiral recognition between the reagents (10:1) to give products which may be converted to β,γ-dimethyl-γ-lactones possessing trans- or cis- stereochemistry. © 1989.
Publication status:
Published

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Journal:
TETRAHEDRON LETTERS More from this journal
Volume:
30
Issue:
5
Pages:
587-590
Publication date:
1989-01-01
DOI:
ISSN:
0040-4039
Language:
English
Pubs id:
pubs:168597
UUID:
uuid:0a655165-d9d7-4c9e-a858-e11faf788759
Local pid:
pubs:168597
Source identifiers:
168597
Deposit date:
2012-12-19

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