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Cyclodextrin-templated porphyrin nanorings.

Abstract:

α- and β-cyclodextrins have been used as scaffolds for the synthesis of six- and seven-legged templates by functionalizing every primary CH2OH with a 4-pyridyl moiety. Although these templates are flexible, they are very effective for directing the synthesis of macrocyclic porphyrin oligomers consisting of six or seven porphyrin units. The transfer of chirality from the cyclodextrin templates to their nanoring hosts is evident from NMR and circular dichroism spectroscopy. Surprisingly, the me...

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Publication status:
Published

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Publisher copy:
10.1002/anie.201402917

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
53
Issue:
30
Pages:
7770-7773
Publication date:
2014-07-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
469452
Language:
English
Keywords:
Pubs id:
pubs:469452
UUID:
uuid:0a3d553d-9d26-4b6c-b749-3754b986c051
Local pid:
pubs:469452
Deposit date:
2014-06-17

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