- Abstract:
-
Reaction of Ag[CB11H12] with [Rh(COD)Cl]2 (COD=1,4-cyclooctadiene) affords the complex [Rh(COD)(η2-CB11H12)] (2), which has been characterised by NMR spectroscopy and X-ray crystallography. The solid-state structure shows that the carborane is co-ordinated to the rhodium by two 3c-2e Rh-H-B bonds. The solution fluxional behaviour of the {Rh(COD)} fragment over the surface of the cage is discussed. The carborane ligand in 2 is displaced by THF to give the crystallographically characterised com...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/S0022-328X(00)00608-2
-
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- Journal:
- JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Volume:
- 614
- Pages:
- 113-119
- Publication date:
- 2000-12-01
- DOI:
- ISSN:
-
0022-328X
- URN:
-
uuid:0a3bc06a-701f-46ce-a009-777cc30c17af
- Source identifiers:
-
51719
- Local pid:
- pubs:51719
- Language:
- English
- Keywords:
- Copyright date:
- 2000
Journal article
Rhodium cyclooctadiene complexes of the weakly co-ordinating carborane anion [closo-CB11H12](-). Isolation and crystal structures of [(COD)Rh(eta(2)-CB11H12)] and [(COD)Rh(THF)(2)][CB11H12]
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