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Journal article

Mono-, di- and tri-dentate binding modes of a substituted isocytosine derivative in complexes of palladium and zinc

Abstract:

The crystal and molecular structures of three metal complexes of the pyrimidine derivative, 1-(2-hydroxyethyl)-(2-aminoethyl-N2)-5-methylisocytosine reveal that, as a ligand, this heterocyclic base exhibited a diverse range of co-ordination modes. With zinc(II), monodentate co-ordination via the carbonyl oxygen of the pyrimidine base was observed. In the case of palladium(II), both a didentate mode, via endo- and exo-cyclic nitrogen donors, and a tridentate mode, involving exocyclic nitrogens...

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Publication status:
Published

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Publisher copy:
10.1039/a800271a

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
12
Pages:
2001-2006
Publication date:
1998-06-21
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
Language:
English
Pubs id:
pubs:115941
UUID:
uuid:0a38166e-1288-41e4-926d-b499d4e85c83
Local pid:
pubs:115941
Source identifiers:
115941
Deposit date:
2012-12-19

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