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A total synthesis of salinosporamide A

Abstract:
Salinosporamide A is a β‐lactone proteasome inhibitor currently in clinical trials for the treatment of multiple‐myeloma. Herein we report a short synthesis of this small, highly functionalized, biologically important natural product that uses an oxidative radical cyclization as a key step and allows for the preparation of gram quantities of advanced synthetic intermediates.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/chem.201800046

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Somerville College
Role:
Author


Publisher:
Wiley
Journal:
Chemistry - A European Journal More from this journal
Volume:
24
Issue:
26
Pages:
6747-6754
Publication date:
2018-03-09
Acceptance date:
2018-02-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539


Keywords:
Pubs id:
pubs:823086
UUID:
uuid:0a25806e-f4d2-49ad-baba-dd24dd0c558c
Local pid:
pubs:823086
Source identifiers:
823086
Deposit date:
2018-02-07
ARK identifier:

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