- Abstract:
- The dc Stark effect is studied for autoionising Rydberg states of H2 converging on the ν+=2 ionisation limit. The levels (n = 13-22) are excited from the ground state using a coherent XUV source (bandwidth ≈ 1 cm-1) and are strongly perturbed by the field (15-2000 V/cm). Many new states are observed, including the high-/hydrogenic manifolds. A detailed Stark map is obtained for the first time, and a matrix diagonalisation calculation of field-induced state mixing is carried out to explain some of the observed features. © 1991.
- Publication status:
- Published
- Publisher copy:
- 10.1016/S0009-2614(91)85047-Z
-
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- Journal:
- CHEMICAL PHYSICS LETTERS
- Volume:
- 185
- Issue:
- 3-4
- Pages:
- 199-205
- Publication date:
- 1991-10-18
- DOI:
- ISSN:
-
0009-2614
- URN:
-
uuid:0a222521-770e-4a0d-acf4-0c3900bbdfaa
- Source identifiers:
-
43635
- Local pid:
- pubs:43635
- Language:
- English
- Copyright date:
- 1991
Journal article
OBSERVATION OF THE STARK-EFFECT IN AUTOIONIZING RYDBERG STATES OF MOLECULAR-HYDROGEN
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