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Exploring carbohydrate-peptide interactions in the gas phase: structure and selectivity in complexes of pyranosides with N-acetylphenylalanine methylamide.

Abstract:

The physical basis of carbohydrate-peptide interactions has been explored by probing the structures of a series of complexes generated in a solvent-free environment under molecular beam conditions. A combination of double-resonance IR-UV spectroscopy and quantum-chemical calculations has established the structures of complexes of the model, N-acetyl-L-phenylalanine methylamide, bound to the α and β anomers of methyl D-gluco- and D-galactopyranoside as guests. In all cases, the carbohydrates a...

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Publication status:
Published

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Publisher copy:
10.1021/ja109664k

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society More from this journal
Volume:
133
Issue:
12
Pages:
4548-4557
Publication date:
2011-03-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Keywords:
Pubs id:
pubs:124312
UUID:
uuid:0a0cea7d-13d1-49d7-a546-3133ec29029c
Local pid:
pubs:124312
Source identifiers:
124312
Deposit date:
2012-12-19

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