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PHOTODISSOCIATION DYNAMICS OF HCOOH(A)

Abstract:

The technique of Doppler-resolved, polarised LIF spectroscopy has been employed in a study of the energy and momenta disposal in the OH fragments generated via photodissociation of HCOOH (Ã 1A″) at 225 nm. The majority of the excess energy resides in fragment translation (≈ 78%) and internal excitation of the HCO fragment (≈ 12%). An analysis of the Doppler-resolved profiles reveals that OH rotational excitation (for N″ ≈ 6) is generated primarily by out-of-plane C-OH torsional motion in the ...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
149
Issue:
1
Pages:
45-50
Publication date:
1988-08-05
DOI:
ISSN:
0009-2614
URN:
uuid:0a05b479-38d0-4764-af85-cf85c8592bb8
Source identifiers:
52547
Local pid:
pubs:52547
Language:
English

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