- Abstract:
-
The crystal and magnetic structures of Sr4MMn2O 9 (M=Cu, Zn) have been refined from neutron powder diffraction data. These trigonal compounds (space group P321, a=9.5918(1), c=7.8114(1)Å (Cu); a=9.5894(1), c=7.5039(1)Å (Zn)) are n=3 members of the series A 3n+3MnBn+3O6n+9, with each unit cell containing three offset [001] polyhedral chains, each of which ideally contains a 1:1 ratio of B2O9 units and MO6 trigonal prisms. In fact anti-site disorder between Mn and M is observed, and for M=Cu th...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/S0022-4596(03)00351-7
-
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- Journal:
- JOURNAL OF SOLID STATE CHEMISTRY
- Volume:
- 176
- Issue:
- 1
- Pages:
- 88-96
- Publication date:
- 2003-11-15
- DOI:
- ISSN:
-
0022-4596
- URN:
-
uuid:09f03d92-4c49-4b7f-9499-1e777d60c521
- Source identifiers:
-
38887
- Local pid:
- pubs:38887
- Language:
- English
- Copyright date:
- 2003
Journal article
Crystal and magnetic structures of Sr4MMn2O9 (M = Cu or Zn)
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