Unravelling the role of redox active sites in nitrogen doped cerium oxide for associative ammonia decomposition

Journal article

The catalytic decomposition of ammonia under mild conditions is a promising route for green hydrogen production. However, conventional dissociative ammonia decomposition pathways over metal sites are suffering from the Brønsted−Evans−Polanyi (BEP) constraint which establishes an inverse correlation between atomic N binding energy and the N-H bond dissociation energy. Herein, we report a ruthenium-supported nitrogen-doped cerium oxide (Ru/N-CeO2) catalyst that breaks this limitation and exhibits significantly enhanced catalytic activity compared to its undoped counterpart. Furthermore, we reveal that N dopants can act as independent active sites, enabling an associative mechanism distinct from the conventional Ru-driven pathway. Comprehensive isotopic labelling experiments together with computational techniques elucidate the reaction mechanism over the N site and reveal a distinct correlation between the location of the active site and catalytic activity. The proximal N site exhibits the highest activity, challenging the conventional view that activity is dominated by metal–support interfacial sites. While N doping is a commonly used approach for surface modification, our findings show that it can also alter the reaction mechanism by introducing new active sites. These insights offer valuable guidance for the rational design of catalytic supports in ammonia decomposition and open new directions for catalytic systems limited by scaling relationships in heterogenous catalysis.

Authors: Ye, D; Luo, M; Liu, X; Foo, C; Duan, M

• Publication status: Published
• Peer review status: Peer reviewed
• Publisher: Nature Research
• Journal: Nature Communications
• Volume: 17
• Issue: 1
• Article number: 3892
• Publication date: 2026-03-13
• Acceptance date: 2026-02-25
• DOI: 10.1038/s41467-026-70330-5
• EISSN: 2041-1723
• ISSN: 2041-1723
• Language: English
• Keywords: Catalysis; Active site; Ammonia; Cerium oxide; Dissociation (chemistry); Decomposition; Associative substitution; Oxide; Redox