Journal article
Asymmetric synthesis of sulfinyl-substituted arene chromium tricarbonyl complexes
- Abstract:
-
The synthesis of (SRSs[(phenylsulfinyl)benzene] chromium tricarbonyl 5 and (SRSs)-[(p-tolylsulfiny))benzene] chromium tricarbonyl 6 is achieved via a nucleophilic displacement reaction between the anion derived from (benzene) chromium tricarbonyl 9 and a suitable sulfinate ester. Replacing the sulfinate ester with a chiral sulfinyl-transfer reagent allows the isolation of the non-racemic sulfinyl-substituted complexes with good enantioselectivities (ee 80-89%) under optimised conditions. The ...
Expand abstract
- Publication status:
- Published
Actions
Authors
Bibliographic Details
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
- Issue:
- 23
- Pages:
- 3405-3412
- Publication date:
- 1999-01-01
- DOI:
- EISSN:
-
1364-5463
- ISSN:
-
0300-922X
Item Description
- Language:
- English
- Pubs id:
-
pubs:110614
- UUID:
-
uuid:09a2a2ce-9abe-4015-a101-dd9833f322a2
- Local pid:
- pubs:110614
- Source identifiers:
-
110614
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1999
Metrics
If you are the owner of this record, you can report an update to it here: Report update to this record