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Asymmetric synthesis of sulfinyl-substituted arene chromium tricarbonyl complexes

Abstract:

The synthesis of (SRSs[(phenylsulfinyl)benzene] chromium tricarbonyl 5 and (SRSs)-[(p-tolylsulfiny))benzene] chromium tricarbonyl 6 is achieved via a nucleophilic displacement reaction between the anion derived from (benzene) chromium tricarbonyl 9 and a suitable sulfinate ester. Replacing the sulfinate ester with a chiral sulfinyl-transfer reagent allows the isolation of the non-racemic sulfinyl-substituted complexes with good enantioselectivities (ee 80-89%) under optimised conditions. The ...

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Publication status:
Published

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Publisher copy:
10.1039/a907590i

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 More from this journal
Issue:
23
Pages:
3405-3412
Publication date:
1999-01-01
DOI:
EISSN:
1364-5463
ISSN:
0300-922X
Language:
English
Pubs id:
pubs:110614
UUID:
uuid:09a2a2ce-9abe-4015-a101-dd9833f322a2
Local pid:
pubs:110614
Source identifiers:
110614
Deposit date:
2012-12-19

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