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RING-DISC ELECTRODES .18. COLLECTION EFFICIENCY FOR HIGH-FREQUENCY AC

Abstract:
By using contour integration to invert the Laplace transforms, an analytical expression for the first order kinetic collection efficiency for a ring-disc electrode can be obtained for values of κ > 3. One can then obtain analytical results for the phase shift and amplitude of the ring current with respect to the disc current when an alternating current is passed through the disc. Hence, theoretical results for the complete frequency range can now be obtained. Theory and experiment are found to be in good agreement.
Publication status:
Published

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Publisher copy:
10.1039/f19787401007

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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I
Volume:
74
Issue:
0
Pages:
1007-1019
Publication date:
1978-01-01
DOI:
ISSN:
0300-9599
URN:
uuid:0984a095-e555-404b-917d-2e1d55a979a8
Source identifiers:
41724
Local pid:
pubs:41724
Language:
English

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