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Oxapolycycles from one-pot cross-metathesis/carbonyl ylide formation-intramolecular cycloaddition of alpha-diazo-beta-keto esters

Abstract:
Chemoselective cross-metathesis of unsaturated α-diazo-β-keto esters using Grubbs' 2nd generation catalyst, followed by Rh 2(OAc)4-catalysed tandem carbonyl ylide formation-intramolecular cycloaddition is demonstrated. The two different catalytic metallocarbene transfer reactions have also been successfully carried out in a one-pot procedure, which allows rapid generation of molecular complexity in a single operation. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/adsc.200600306

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Angrish, D More by this author
Journal:
ADVANCED SYNTHESIS and CATALYSIS
Volume:
348
Issue:
16-17
Pages:
2509-2514
Publication date:
2006-11-05
DOI:
EISSN:
1521-3897
ISSN:
1615-4150
URN:
uuid:096a2fc4-742b-490b-a2c4-bcaa87b4c2f7
Source identifiers:
40191
Local pid:
pubs:40191

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