Journal article
Oxapolycycles from one-pot cross-metathesis/carbonyl ylide formation-intramolecular cycloaddition of alpha-diazo-beta-keto esters
- Abstract:
- Chemoselective cross-metathesis of unsaturated α-diazo-β-keto esters using Grubbs' 2nd generation catalyst, followed by Rh 2(OAc)4-catalysed tandem carbonyl ylide formation-intramolecular cycloaddition is demonstrated. The two different catalytic metallocarbene transfer reactions have also been successfully carried out in a one-pot procedure, which allows rapid generation of molecular complexity in a single operation. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/adsc.200600306
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Bibliographic Details
- Journal:
- ADVANCED SYNTHESIS and CATALYSIS
- Volume:
- 348
- Issue:
- 16-17
- Pages:
- 2509-2514
- Publication date:
- 2006-11-01
- DOI:
- EISSN:
-
1521-3897
- ISSN:
-
1615-4150
- Source identifiers:
-
40191
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:40191
- UUID:
-
uuid:096a2fc4-742b-490b-a2c4-bcaa87b4c2f7
- Local pid:
- pubs:40191
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2006
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