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Nanosized polymetallic resorcinarene-based host assemblies that strongly bind fullerenes.

Abstract:

Polymetallic nanodimensional assemblies have been prepared via metal directed assembly of dithiocarbamate functionalized cavitand structural frameworks with late transition metals (Ni, Pd, Cu, Au, Zn, and Cd). The coordination geometry about the metal centers is shown to dictate the architecture adopted. X-ray crystallographic studies confirm that square planar coordination geometries result in "cagelike" octanuclear complexes, whereas square-based pyramidal metal geometries favor hexanuclear...

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Publication status:
Published

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Publisher copy:
10.1021/ja060982t

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Journal:
Journal of the American Chemical Society More from this journal
Volume:
128
Issue:
21
Pages:
6990-7002
Publication date:
2006-05-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:33482
UUID:
uuid:095ae258-3158-4b41-9ff2-f211d9dbffeb
Local pid:
pubs:33482
Source identifiers:
33482
Deposit date:
2012-12-19

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