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Exploiting a novel size exclusion phenomenon for enantioselective acid/base cascade catalysis.

Abstract:
A novel size exclusion phenomenon between PS-BEMP and sterically bulky BPAs, has been discovered and exploited in a one-pot base-catalysed Michael addition/acid-catalysed enantioselective N-acyliminium cyclisation cascade, allowing the preparation of structurally complex β-carbolines with moderate to good enantiocontrol.
Publication status:
Published

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Publisher copy:
10.1039/c2cc32258g

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
48
Issue:
51
Pages:
6351-6353
Publication date:
2012-05-23
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
332761
Language:
English
Pubs id:
pubs:332761
UUID:
uuid:08f0df8b-cfb0-47ee-90cd-34324ccbf593
Local pid:
pubs:332761
Deposit date:
2013-11-17

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