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Localization of large polarons in the disordered Holstein model

Abstract:

We solve the disordered Holstein model via the density-matrix renormalization group method to investigate the combined roles of electron-phonon coupling and disorder on the localization of a single charge or exciton. The parameter regimes chosen, namely the adiabatic regime, ω/4t0=ω′<1, and the large polaron regime, λ<1, are applicable to most conjugated polymers. We show that as a consequence of the polaron effective mass diverging in the adiabatic limit (defined as ω′→0 subject to fix...

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Publication status:
Published

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Publisher copy:
10.1103/PhysRevB.89.155434

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Publisher:
American Physical Society
Journal:
Physical Review B
Volume:
89
Issue:
15
Publication date:
2014-04-28
DOI:
EISSN:
1550-235X
ISSN:
1098-0121
Language:
English
Pubs id:
pubs:465501
UUID:
uuid:08d1ac46-99d4-4d29-85f1-5a82b6e9bc22
Local pid:
pubs:465501
Source identifiers:
465501
Deposit date:
2014-11-08

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