Journal article
Stripping voltammetry of bismuth at Au(111): Mathematical modelling and numerical simulation
- Abstract:
-
The electrodeposition of bismuth on a gold electrode consists of an underpotential deposition (UPD) and an overpotential deposition (OPD) of bulk bismuth which follows nucleation on the UPD. Mathematical modelling and numerical simulations have been compared with experimental data to propose a mechanism for the deposition and stripping of bulk bismuth on a Au(1 1 1) electrode from a 1 mM Bi3+/0.1 M HClO4 solution. This mechanism has first order kinetics with respect to the concentration of Bi...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/j.jelechem.2008.01.003
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Bibliographic Details
- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 616
- Issue:
- 1-2
- Pages:
- 38-44
- Publication date:
- 2008-05-01
- DOI:
- ISSN:
-
1572-6657
- Source identifiers:
-
40782
Item Description
- Language:
- English
- Keywords:
- UUID:
-
uuid:08cd0f68-51ea-4cff-8f93-245cf4217abe
- Local pid:
- pubs:40782
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2008
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