Journal article
New approach to electrode kinetic measurements in square-wave voltammetry: amplitude-based quasireversible maximum.
- Abstract:
-
The influence of the potential pulse height of square-wave voltammetry (SWV) (i.e., the SW amplitude) is studied for a variety of quasireversible electrode mechanisms, including a simple solution-phase electrode reaction at a planar or spherical electrode, a solution phase electrode reaction coupled with a reversible follow-up chemical reaction, and a diffusionless surface confined electrode reaction. The electrode kinetics of all the electrode mechanisms depends critically on the SW amplitud...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- Analytical chemistry
- Volume:
- 85
- Issue:
- 11
- Pages:
- 5586-5594
- Publication date:
- 2013-06-01
- DOI:
- EISSN:
-
1520-6882
- ISSN:
-
0003-2700
Item Description
- Language:
- English
- UUID:
-
uuid:08c5c4d6-1d37-4037-9b2a-2812f4750afa
- Local pid:
- pubs:401830
- Source identifiers:
-
401830
- Deposit date:
- 2013-11-17
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- Copyright date:
- 2013
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