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Journal article

New approach to electrode kinetic measurements in square-wave voltammetry: amplitude-based quasireversible maximum.

Abstract:

The influence of the potential pulse height of square-wave voltammetry (SWV) (i.e., the SW amplitude) is studied for a variety of quasireversible electrode mechanisms, including a simple solution-phase electrode reaction at a planar or spherical electrode, a solution phase electrode reaction coupled with a reversible follow-up chemical reaction, and a diffusionless surface confined electrode reaction. The electrode kinetics of all the electrode mechanisms depends critically on the SW amplitud...

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Publication status:
Published

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Publisher copy:
10.1021/ac4008573

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Analytical chemistry
Volume:
85
Issue:
11
Pages:
5586-5594
Publication date:
2013-06-01
DOI:
EISSN:
1520-6882
ISSN:
0003-2700
Language:
English
UUID:
uuid:08c5c4d6-1d37-4037-9b2a-2812f4750afa
Local pid:
pubs:401830
Source identifiers:
401830
Deposit date:
2013-11-17

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