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UV photodissociation dynamics of iodobenzene: effects of fluorination.

Abstract:

The UV photochemistry of various fluorinated iodobenzenes (4-fluoro-, 2,4-difluoro-, 3,5-difluoro-, and perfluoro-iodobenzene) has been investigated at many wavelengths by velocity map imaging, time-resolved near infrared absorption spectroscopy and (spin-orbit resolved) ab initio calculations of the ground and excited state potentials along the C-I stretch coordinate, R(C-I). The textbook description of the near UV photochemistry of CH(3)I, i.e., σ∗←n excitation to the (3)Q(0+) state, follow...

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Publication status:
Published

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Publisher copy:
10.1063/1.3696892
Journal:
Journal of chemical physics More from this journal
Volume:
136
Issue:
12
Pages:
124313
Publication date:
2012-03-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Language:
English
Pubs id:
pubs:331035
UUID:
uuid:08bf26ef-b733-42fc-8cea-1ef11c8c67ab
Local pid:
pubs:331035
Source identifiers:
331035
Deposit date:
2012-12-19

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