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Electron paramagnetic resonance study of ErSc2NC80

Abstract:

We present an electron paramagnetic resonance (EPR) study of ErSc2N@C80 fullerene in which there are two Er3+ sites corresponding to two different configurations of the ErSc2N cluster inside the C80 cage. For each configuration, the EPR spectrum is characterized by a strong anisotropy of the g factors (gx,y = 2.9, gz = 13.0 and gx,y = 5.3, gz = 10.9). Illumination within the cage absorption range (<600 nm) induces a rearrangement of the ErSc2N cluster inside the cage. We follow the tempora...

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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
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Source identifiers:
620276
Keywords:
Pubs id:
pubs:620276
UUID:
uuid:08a405f8-fd0e-4c48-bdce-a549b1ac628d
Local pid:
pubs:620276
Deposit date:
2016-05-11

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