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A general route to alkylene-, arylene-, or benzylene-bridged ditin hexachlorides and hexaalkynides

Abstract:
The preparation of alkylene-, arylene-, or benzylene-bridged ditin hexachlorides in high yields from the reaction of the corresponding hexacyclohexylated compounds with tin tetrachloride is described. The tetragonal geometry of the tin atom of 1,4-bis(trichlorostannyl)-butane in the solid state indicates that no intramolecular or intermolecular interaction involving either end of the molecule exists in this compound. The ditin hexachlorides were successfully transformed in the corresponding hexaalkynides, precursors of hybrid materials.
Publication status:
Published

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Publisher copy:
10.1021/om0202468

Authors


Jousseaume, B More by this author
Toupance, T More by this author
Lahcini, M More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Journal:
ORGANOMETALLICS
Volume:
21
Issue:
22
Pages:
4590-4594
Publication date:
2002-10-28
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:0895948a-f98f-40a6-81da-22b13c3e5e48
Source identifiers:
51218
Local pid:
pubs:51218
Language:
English

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