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Journal article

The theory of the ac voltammetry of reversible electrode processes at tubular electrodes

Abstract:
A theory describing the alternating current response to an ac potential superimposed on a de potential is described for reversible electrode reactions at both tubular and channel electrodes. Al high frequencies the current is phase shifted through π 4 as predicted by the classical Warburg impedance expression. At lower frequencies the effect of convection causes the phase shift to fall below π 4.
Publication status:
Published

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Journal:
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry More from this journal
Volume:
145
Issue:
1
Pages:
35-41
Publication date:
1983-01-01
DOI:
ISSN:
1572-6657
Language:
English
UUID:
uuid:08415189-e290-498d-a7c4-2f5533955de3
Local pid:
pubs:52800
Source identifiers:
52800
Deposit date:
2012-12-19

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