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Intramolecular C-C agostic complexes: C-C sigma interactions by another name.

Abstract:

In this comprehensive review the developments in the synthesis, characterization and reactivity of complexes (s-, d- and f-block) in which a C-C single bond interacts with a metal centre are discussed: so called C-CM agostic complexes. Such species are of significant interest with regard to structure and bonding, the activation of C-C single bonds and, thus, catalytic methods of C-C bond formation (or activation). Examples of C-C agostic complexes of early and later transition metals, actinid...

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Publication status:
Published

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Publisher copy:
10.1039/c3cs60295h

Authors


Etienne, M More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Chemical Society reviews
Volume:
43
Issue:
1
Pages:
242-259
Publication date:
2014-01-05
DOI:
EISSN:
1460-4744
ISSN:
0306-0012
URN:
uuid:0838c469-3417-447b-b0d4-5db3e0bb7d16
Source identifiers:
443401
Local pid:
pubs:443401
Language:
English

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