Intramolecular C-C agostic complexes: C-C sigma interactions by another name.
In this comprehensive review the developments in the synthesis, characterization and reactivity of complexes (s-, d- and f-block) in which a C-C single bond interacts with a metal centre are discussed: so called C-CM agostic complexes. Such species are of significant interest with regard to structure and bonding, the activation of C-C single bonds and, thus, catalytic methods of C-C bond formation (or activation). Examples of C-C agostic complexes of early and later transition metals, actinid...Expand abstract
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