- Abstract:
-
The binuclear allenyl complex [Fe2(CO)6(μ-PPh2){μ-η 1:η2α,β-(H)C α=Cβ=CγH2}] (1) has been prepared, and its reactivity with organolithium nucleophiles is described. Prop-2-yne bromide reacts with [Fe2(CO)7(μ-PPh2)]-Na +, via an SN2 mechanism, to give [Fe2(CO)6(μ-PPh2){μ-η1: η2α,β-(H)Cα=C β=CγH2}], the first example of a phosphido-bridged allenyl complex. The molecular structure of [Fe2(CO)6(μ-PPh2){μ-η 1:η2-(H)Cα=Cβ=C γH2}]: (1) was determined by single-crystal X-ray diffraction and shows tha...
Expand abstract - Publisher copy:
- 10.1021/om970171l
-
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- Journal:
- Organometallics
- Volume:
- 16
- Issue:
- 14
- Pages:
- 3221-3228
- Publication date:
- 1997-07-08
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- URN:
-
uuid:07bc8b37-cadf-4cc2-95be-d1ab3989a6cd
- Source identifiers:
-
118882
- Local pid:
- pubs:118882
- Language:
- English
- Copyright date:
- 1997
Journal article
Addition of organolithium nucleophiles to the diiron allenyl complex [Fe2(CO)6(μ-PPh2){μ-η1: η2 α,β-(H)Cα=Cβ =CγH2}]:Synthesis and characterization of organodiiron-coordinated β,γ-unsaturated ketones
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