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Addition of organolithium nucleophiles to the diiron allenyl complex [Fe2(CO)6(μ-PPh2){μ-η1: η2 α,β-(H)Cα=Cβ =CγH2}]:Synthesis and characterization of organodiiron-coordinated β,γ-unsaturated ketones

Abstract:

The binuclear allenyl complex [Fe2(CO)6(μ-PPh2){μ-η 1:η2α,β-(H)C α=Cβ=CγH2}] (1) has been prepared, and its reactivity with organolithium nucleophiles is described. Prop-2-yne bromide reacts with [Fe2(CO)7(μ-PPh2)]-Na +, via an SN2 mechanism, to give [Fe2(CO)6(μ-PPh2){μ-η1: η2α,β-(H)Cα=C β=CγH2}], the first example of a phosphido-bridged allenyl complex. The molecular structure of [Fe2(CO)6(μ-PPh2){μ-η 1:η2-(H)Cα=Cβ=C γH2}]: (1) was determined by single-crystal X-ray diffraction and shows tha...

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Publisher copy:
10.1021/om970171l

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Organometallics
Volume:
16
Issue:
14
Pages:
3221-3228
Publication date:
1997-07-08
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Source identifiers:
118882
Language:
English
Pubs id:
pubs:118882
UUID:
uuid:07bc8b37-cadf-4cc2-95be-d1ab3989a6cd
Local pid:
pubs:118882
Deposit date:
2012-12-19

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