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A metathesis-based approach to the synthesis of 2-pyridones and pyridines.

Abstract:
The ring-closing metathesis reaction has been successfully employed to form a range of dihydropyridone intermediates, which are in the correct oxidation state to undergo a base-induced elimination to reveal the aromatic 2-pyridone. This mild and novel approach to six-membered heteroaromatic compounds then provides access to a wide variety of substituted pyridines in excellent overall yield.
Publication status:
Published

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Publisher copy:
10.1021/ol702684d

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Organic letters More from this journal
Volume:
10
Issue:
2
Pages:
285-288
Publication date:
2008-01-01
DOI:
EISSN:
1523-7052
ISSN:
1523-7060
Language:
English
Keywords:
Pubs id:
pubs:34087
UUID:
uuid:07b9c166-ab0b-424d-b53d-4da45e446773
Local pid:
pubs:34087
Source identifiers:
34087
Deposit date:
2012-12-19

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