Journal article
Alkene ozonolysis in the presence of diazo functionality: accessing an intermediate for squalestatin synthesis
- Abstract:
- Studies on both the propensity for intramolecular cycloaddition between diazo and alkene functionality, and the tolerance of α-substituted α-diazoesters towards ozone in the presence of an alkene, led to chemoselective alkene ozonolysis of an ε-unsaturated-α-diazoester to give a key racemic diazoketone for the synthesis of 6,7-dideoxysqualestatin H5.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Authors
Bibliographic Details
- Publisher:
- Thieme Gruppe Publisher's website
- Journal:
- Synthesis Journal website
- Volume:
- 51
- Issue:
- 22
- Pages:
- 4231-4238
- Publication date:
- 2019-09-13
- Acceptance date:
- 2019-07-26
- DOI:
- EISSN:
-
1437-210X
- ISSN:
-
0039-7881
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:1053917
- UUID:
-
uuid:07a488bf-0e53-40b3-80bb-49442e72287b
- Local pid:
- pubs:1053917
- Source identifiers:
-
1053917
- Deposit date:
- 2019-09-17
Terms of use
- Copyright holder:
- Georg Thieme Verlag
- Copyright date:
- 2019
- Rights statement:
- © 2019. Thieme. All rights reserved.
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from Thieme Gruppe at: https://doi.org/10.1055/s-0039-1690180
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