Journal article
Copper(I) O,O '-dialkyldithiophosphate clusters: EXAFS, NMR and X-ray diffraction studies
- Abstract:
-
Copper K-edge EXAFS data for six polycrystalline cubic cluster compounds, {Cu8[S2P(OR)2]6(μ8-S)} with R = Et, nPr, iPr, nBu, iBu and iAm, show that the architecture of their Cu8(S2P)2S cores is fairly rigid and independent of both length and branching of the alkyl chain, and that the structure of the cluster is maintained in acetone solution. Solid-state 31P CP-MAS and static 65Cu NMR data for {Cu8[S2P(OnPr)2]6(μ8-S)} and {Cu8[S2P(OEt)2]6(μ8-S)} show similarities in the icosahedral O,O′-dialk...
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- Publication status:
- Published
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- Publisher copy:
- 10.1080/00958970600842856
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Bibliographic Details
- Journal:
- JOURNAL OF COORDINATION CHEMISTRY
- Volume:
- 60
- Issue:
- 5
- Pages:
- 517-525
- Publication date:
- 2007-01-01
- DOI:
- EISSN:
-
1029-0389
- ISSN:
-
0095-8972
- Source identifiers:
-
321991
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:321991
- UUID:
-
uuid:0798df9c-01c3-42a6-a4d8-ca136af974b1
- Local pid:
- pubs:321991
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2007
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