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Copper(I) O,O '-dialkyldithiophosphate clusters: EXAFS, NMR and X-ray diffraction studies

Abstract:

Copper K-edge EXAFS data for six polycrystalline cubic cluster compounds, {Cu8[S2P(OR)2]6(μ8-S)} with R = Et, nPr, iPr, nBu, iBu and iAm, show that the architecture of their Cu8(S2P)2S cores is fairly rigid and independent of both length and branching of the alkyl chain, and that the structure of the cluster is maintained in acetone solution. Solid-state 31P CP-MAS and static 65Cu NMR data for {Cu8[S2P(OnPr)2]6(μ8-S)} and {Cu8[S2P(OEt)2]6(μ8-S)} show similarities in the icosahedral O,O′-dialk...

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Publication status:
Published

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Publisher copy:
10.1080/00958970600842856

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
JOURNAL OF COORDINATION CHEMISTRY
Volume:
60
Issue:
5
Pages:
517-525
Publication date:
2007-01-01
DOI:
EISSN:
1029-0389
ISSN:
0095-8972
URN:
uuid:0798df9c-01c3-42a6-a4d8-ca136af974b1
Source identifiers:
321991
Local pid:
pubs:321991

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