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Thesis

Higher-Order Cycloisomerisations of Enynamides

Abstract:

This thesis describes the development of a novel transformation of ynamides, and addresses more general questions of asymmetric cycloisomerisation. The rhodiumcatalysed [5+2] cycloisomerisation of ynamide vinylcyclopropanes A1 to [5.3.0]- heterobicycles A2 is established (Scheme i). We design a versatile substrate synthesis, which allows the preparation of diversely substituted enynamide substrates. Under achiral rhodium catalysis, the extent of substrate diastereo- and ...

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Division:
MPLS
Department:
History Faculty
Sub department:
Archaeology Research Lab
Department:
University of Oxford
Role:
Author

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Role:
Supervisor
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
Subjects:
UUID:
uuid:07677f16-f1ea-443e-b9dd-6239963d3ec4
Deposit date:
2016-08-31

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