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Journal article

Manganese(III)-mediated oxidative free-radical cyclisations of allenyl malonates

Abstract:: The regioselective synthesis of alkenylcyclanones by the oxidative radical cyclisation of malonyl radicals onto both allenes and an allylsilane is reported, along with the diastereoselective formation of [3.3.0]-bicyclic γ-lactones from two of these alkenylcyclanones. Furthermore, the cyclisation of 3-, 4- and 5-allenyl malonates on exposure to manganese(III) acetate under both oxidative and reductive termination conditions is reported. © 2009 Elsevier Ltd. All rights reserved.

Publication status:: Published

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APA Style

Curry, L., Hallside, M. S., Powell, L., Sprague, S., & Burton, J. (2009). Manganese(III)-mediated oxidative free-radical cyclisations of allenyl malonates. TETRAHEDRON, 65(52), 10882–10892.

MLA Style

Curry, L., et al. “Manganese(III)-Mediated Oxidative Free-Radical Cyclisations of Allenyl Malonates.” TETRAHEDRON, vol. 65, no. 52, 2009, pp. 10882–92.

Chicago Style

Curry, L, MS Hallside, L Powell, S Sprague, and J Burton. 2009. “Manganese(III)-Mediated Oxidative Free-Radical Cyclisations of Allenyl Malonates.” TETRAHEDRON 65 (52): 10882–92.
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Publisher copy:: 10.1016/j.tet.2009.09.112

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+ Curry, L More by this author

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+ Hallside, MS More by this author

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+ Powell, L More by this author

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+ Sprague, S More by this author

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+ Burton, J More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Organic Chemistry

Role:

Author

Bibliographic Details

Journal:: TETRAHEDRON
Volume:: 65
Issue:: 52
Pages:: 10882-10892
Publication date:: 2009-12-26
DOI:: 10.1016/j.tet.2009.09.112
ISSN:: 0040-4020

Item Description

Language:: English
Pubs id:: pubs:41461
UUID:: uuid:075fa173-7fc0-481f-9f81-2f4d3489167e
Local pid:: pubs:41461
Source identifiers:: 41461
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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