- Abstract:
-
Polycrystalline samples of Nd(18)Li(8)Fe(5)O(39) and Nd(18)Li(8)Co(4)O(39) have been synthesized using a solid-state method and studied by a combination of neutron diffraction, direct and alternating current magnetometry, and, in the case of Nd(18)Li(8)Fe(5)O(39), Mossbauer spectroscopy. Both compounds adopt a cubic structure (space group Pm3n, a(0) approximately 11.9 A) based on intersecting 111 chains made up of alternating octahedral and trigonal-prismatic coordination sites. The Fe(4+) ca...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic801529m
-
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- Journal:
- Inorganic chemistry
- Volume:
- 47
- Issue:
- 23
- Pages:
- 11212-11222
- Publication date:
- 2008-12-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:074e581e-a348-4785-9567-fbcaed1097b7
- Source identifiers:
-
34445
- Local pid:
- pubs:34445
- Language:
- English
- Copyright date:
- 2008
Journal article
Structural chemistry and magnetic properties of Nd18Li8Fe5O39 and Nd18Li8Co4O39: the interplay of cation and spin ordering.
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