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Structural chemistry and magnetic properties of Nd18Li8Fe5O39 and Nd18Li8Co4O39: the interplay of cation and spin ordering.

Abstract:

Polycrystalline samples of Nd(18)Li(8)Fe(5)O(39) and Nd(18)Li(8)Co(4)O(39) have been synthesized using a solid-state method and studied by a combination of neutron diffraction, direct and alternating current magnetometry, and, in the case of Nd(18)Li(8)Fe(5)O(39), Mossbauer spectroscopy. Both compounds adopt a cubic structure (space group Pm3n, a(0) approximately 11.9 A) based on intersecting 111 chains made up of alternating octahedral and trigonal-prismatic coordination sites. The Fe(4+) ca...

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Publication status:
Published

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Publisher copy:
10.1021/ic801529m

Authors


Dutton, SE More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Grandjean, F More by this author
Oh-Ishi, K More by this author
Journal:
Inorganic chemistry
Volume:
47
Issue:
23
Pages:
11212-11222
Publication date:
2008-12-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:074e581e-a348-4785-9567-fbcaed1097b7
Source identifiers:
34445
Local pid:
pubs:34445
Language:
English

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