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Structural variety in ytterbium dicarboxylate frameworks and in situ study diffraction of their solvothermal crystallisation

Abstract:

The ytterbium 1,4-benzenedicarboxylate (BDC) framework [Yb2(BDC)3(DMF)2]·H2O (1) crystallises from a N,N-dimethylformamide (DMF)-rich solution at 80–120 °C. (1) is constructed from infinite chains of dicarboxylate-bridged seven-coordinate Yb atoms, cross-linked in two directions by BDC to yield diamond-shaped channels (sra

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C7CE00481H

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Name:
Engineering and Physical Sciences Research Council
Grant:
EP/I020691
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Name:
Conselho Nacional de Desenvolvimento Científico e Tecnológico
Publisher:
Royal Society of Chemistry
Journal:
CrystEngComm More from this journal
Volume:
19
Issue:
17
Pages:
2424-2433
Publication date:
2017-04-11
Acceptance date:
2017-04-10
DOI:
EISSN:
1466-8033
Pubs id:
pubs:718404
UUID:
uuid:07343e99-ca91-4839-b0c3-10e5dbad4eca
Local pid:
pubs:718404
Source identifiers:
718404
Deposit date:
2017-08-16

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