Journal article
METHYL 2-AZIDO-3-O-BENZYL-2-DEOXY-ALPHA-D-MANNOFURANOSIDE AS A DIVERGENT INTERMEDIATE FOR THE SYNTHESIS OF POLYHYDROXYLATED PIPERIDINES AND PYRROLIDINES - SYNTHESIS OF 2,5-DIDEOXY-2,5-IMINO-D-MANNITOL [2R,5R-DIHYDROXYMETHYL-3R,4R-DIHYDROXYPYRROLIDINE]
- Abstract:
- The synthesis of methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside (1) from D-glucose is reported; the conversions of (1) into derivatives of methyl 3-O-benzyl-2,6-dideoxy-2,6-imino-α-D-mannofuranoside (as precursors for the synthesis of polyhydroxylated piperidines) and into the hydroxylated pyrrrolidine, 2,5-dideoxy-2,5-imino-D-mannitol [2R,5R-dihydroxymethyl-3R,4R-dihydroxypyrrolidine] are described. © 1987.
- Publication status:
- Published
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- Publisher copy:
- 10.1016/S0040-4020(01)90034-1
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Authors
Bibliographic Details
- Journal:
- TETRAHEDRON
- Volume:
- 43
- Issue:
- 5
- Pages:
- 971-978
- Publication date:
- 1987-01-01
- DOI:
- ISSN:
-
0040-4020
- Source identifiers:
-
42756
Item Description
- Language:
- English
- Pubs id:
-
pubs:42756
- UUID:
-
uuid:07300ce1-98a5-43a9-89ee-58945dcce22b
- Local pid:
- pubs:42756
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1987
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