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Mechanism of solid/liquid interfacial reactions. The hydrolytic dissolution of solid triphenylmethyl chloride in aqueous solution

Abstract:

The reaction between solid triphenylmethyl chloride (TPMCl) and water, TPMCl(s) + H2O(l) → TPMOH-(aq) + H+(aq) + Cl-(aq), where TPMOH is triphenylmethyl alcohol, has been investigated using the channel flow cell method. It is found that hydrolysis proceeds via a direct heterogeneous fashion whereby the reaction occurs at the solid-liquid interface rather than in solution after the prior dissolution of TPMCl. Kinetic parameters are reported including the effect of ionic strength. Further, usin...

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Publication status:
Published

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Publisher copy:
10.1021/ja9529145

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY More from this journal
Volume:
118
Issue:
18
Pages:
4419-4426
Publication date:
1996-05-08
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
UUID:
uuid:07209420-0d66-4cd3-addf-3d84a297de4e
Local pid:
pubs:45149
Source identifiers:
45149
Deposit date:
2012-12-19

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