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A demonstration of anion templation and selectivity in pseudorotaxane formation

Abstract:
First- and second-sphere coordination of a chloride anion templates the formation of a [2]pseudorotaxane (see picture) in which a pyridinium diamide threads through the annulus of a macrocyclic isophthalamide wheel. The formation of the pseudorotaxane depends on the nature of the anion involved: the use of a larger anion destabilizes the entire recognition motif.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume:
40
Issue:
19
Pages:
3606-+
Publication date:
2001-01-01
DOI:
ISSN:
1433-7851
Source identifiers:
37984
Language:
English
Keywords:
Pubs id:
pubs:37984
UUID:
uuid:071cf293-e531-47f6-8be1-e2169d3af8cf
Local pid:
pubs:37984
Deposit date:
2012-12-19

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