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MASS-TRANSPORT IN CHANNEL ELECTRODES - THE APPLICATION OF THE BACKWARDS IMPLICIT METHOD TO ELECTRODE-REACTIONS (EC, ECE AND DISP) INVOLVING COUPLED HOMOGENEOUS KINETICS

Abstract:

It is shown how the backwards implicit (BI) method may be applied to the description, under steady-state conditions, of complex electrode reaction mechanisms involving coupled homogeneous kinetics and several kinetic species, taking place at channel electrodes. Specifically the EC, ECE, DISP1 and DISP2 mechanisms are examined, and it is shown how the transport-limited currents and current-voltage curves associated with these processes may be computed. The advantages of the method, particularl...

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Publication status:
Published

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Publisher copy:
10.1039/f19888402155
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I
Volume:
84
Issue:
6
Pages:
2155-2171
Publication date:
1988-01-01
DOI:
ISSN:
0300-9599
Language:
English
UUID:
uuid:0709b925-2723-496f-9790-939c3c421e37
Local pid:
pubs:42888
Source identifiers:
42888
Deposit date:
2012-12-19

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