Journal article icon

Journal article

Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides.

Abstract:
Enantioselective alpha-deprotonation of achiral epoxides 1, 21, and 26 using organolithiums in the presence of (-)-sparteine 2 and subsequent electrophile trapping gives access to enantioenriched trisubstituted epoxides 9-17, 22, 23, 27 and 28 (in up to 86% ee).
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/b309717j

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Organic and biomolecular chemistry More from this journal
Volume:
1
Issue:
23
Pages:
4293-4301
Publication date:
2003-12-01
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
Language:
English
Pubs id:
pubs:32581
UUID:
uuid:06c93de7-5d50-445a-8d7d-ceffc71c5ac0
Local pid:
pubs:32581
Source identifiers:
32581
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP