Journal article

Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides.

Abstract:: Enantioselective alpha-deprotonation of achiral epoxides 1, 21, and 26 using organolithiums in the presence of (-)-sparteine 2 and subsequent electrophile trapping gives access to enantioenriched trisubstituted epoxides 9-17, 22, 23, 27 and 28 (in up to 86% ee).

Publication status:: Published

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APA Style

Hodgson, D., Buxton, T., Cameron, I., Gras, E., & Kirton, E. (2003). Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides. Organic and Biomolecular Chemistry, 1(23), 4293–4301.

MLA Style

Hodgson, D., et al. “Enantioselective Synthesis of Epoxides by Alpha-Deprotonation--Electrophile Trapping of Achiral Epoxides.” Organic and Biomolecular Chemistry, vol. 1, no. 23, 2003, pp. 4293–301.

Chicago Style

Hodgson, D, T Buxton, I Cameron, E Gras, and E Kirton. 2003. “Enantioselective Synthesis of Epoxides by Alpha-Deprotonation--Electrophile Trapping of Achiral Epoxides.” Organic and Biomolecular Chemistry 1 (23): 4293–4301.
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Publisher copy:: 10.1039/b309717j

Authors

+ Hodgson, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Buxton, T More by this author

Role:: Author

+ Cameron, I More by this author

Role:: Author

+ Gras, E More by this author

Role:: Author

+ Kirton, E More by this author

Role:: Author

Journal:: Organic and biomolecular chemistry More from this journal
Volume:: 1
Issue:: 23
Pages:: 4293-4301
Publication date:: 2003-12-01
DOI:: 10.1039/b309717j
EISSN:: 1477-0539
ISSN:: 1477-0520

Language:: English
Pubs id:: pubs:32581
UUID:: uuid:06c93de7-5d50-445a-8d7d-ceffc71c5ac0
Local pid:: pubs:32581
Source identifiers:: 32581
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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