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Structural chemistry and magnetic properties of La2LiRuO6

Abstract:

A combination of magnetometry, electron microscopy, neutron diffraction and 7Li MASNMR spectroscopy has been used to determine that La 2LiRuO6 has a monoclinic perovskite-related structure (space group P21/n, a=5.5555(2), b=5.5977(2), c=7.8454(3)Å, β=90.020(5)° at 300K) with a 1:1 ordered arrangement of Li+ and Ru5+ cations occupying the six-coordinate sites. The compound is antiferromagnetic (type I) below 30K with an ordered magnetic moment of 2.2(2)μB per Ru. The magnetic properties of thi...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Hervieu, M More by this author
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Volume:
175
Issue:
1
Pages:
20-26
Publication date:
2003-10-05
DOI:
ISSN:
0022-4596
URN:
uuid:06c63ceb-e542-408a-9ef8-e0a1245a88a4
Source identifiers:
38760
Local pid:
pubs:38760

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