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Iodo-imidazolium salts: halogen bonding in crystals and anion-templated pseudorotaxanes

Abstract:
The 2-iodoimidazolium group is exploited in the anion-templated assembly of pseudorotaxanes with isophthalamide containing macrocycles. Crystallographic and solution-phase studies illustrate that the iodo-imidazolium motif is a potent halogen bond donor, forming the most stable interpenetrated assemblies in solution with the chloride anion template. © 2013 The Royal Society of Chemistry.
Publication status:
Published

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Publisher copy:
10.1039/c2ce26020d

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
CRYSTENGCOMM
Volume:
15
Issue:
16
Pages:
3076-3081
Publication date:
2013-01-01
DOI:
EISSN:
1466-8033
ISSN:
1466-8033
URN:
uuid:0626d426-f908-481a-b8b6-6b6a72c554f8
Source identifiers:
405078
Local pid:
pubs:405078
Language:
English

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