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Group 5 imido complexes derived from diamido-pyridine ligands.

Abstract:

Reaction of the vanadium(V) imide [V(NAr)Cl(3)(THF)] (Ar = 2,6-C(6)H(3)(i)()Pr(2)) with the diamino-pyridine derivative MeC(2-C(5)H(4)N)(CH(2)NHSiMe(2)(t)()Bu)(2) (abbreviated as H(2)N'(2)N(py)) gave modest yields of the vanadium(IV) species [V(NAr)(H(3)N'N' 'N(py))Cl(2)] (1 where H(3)N'N' 'N(py) = MeC(2- C(5)H(4)N)(CH(2)NH(2))(CH(2)NHSiMe(2)(t)()Bu) in which the original H(2)N'(2)N(py) has effectively lost SiMe(2)(t)()Bu (as ClSiMe(2)(t)()Bu) and gained an H atom. Better behaved reactions we...

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Publication status:
Published

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Publisher copy:
10.1021/ic0102541

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
40
Issue:
16
Pages:
3992-4001
Publication date:
2001-07-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:061b7312-1560-4f23-8b06-d3a7f0980c48
Source identifiers:
51024
Local pid:
pubs:51024
Language:
English

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