- Abstract:
-
Reaction of the vanadium(V) imide [V(NAr)Cl(3)(THF)] (Ar = 2,6-C(6)H(3)(i)()Pr(2)) with the diamino-pyridine derivative MeC(2-C(5)H(4)N)(CH(2)NHSiMe(2)(t)()Bu)(2) (abbreviated as H(2)N'(2)N(py)) gave modest yields of the vanadium(IV) species [V(NAr)(H(3)N'N' 'N(py))Cl(2)] (1 where H(3)N'N' 'N(py) = MeC(2- C(5)H(4)N)(CH(2)NH(2))(CH(2)NHSiMe(2)(t)()Bu) in which the original H(2)N'(2)N(py) has effectively lost SiMe(2)(t)()Bu (as ClSiMe(2)(t)()Bu) and gained an H atom. Better behaved reactions we...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic0102541
-
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- Journal:
- Inorganic chemistry
- Volume:
- 40
- Issue:
- 16
- Pages:
- 3992-4001
- Publication date:
- 2001-07-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:061b7312-1560-4f23-8b06-d3a7f0980c48
- Source identifiers:
-
51024
- Local pid:
- pubs:51024
- Language:
- English
- Copyright date:
- 2001
Journal article
Group 5 imido complexes derived from diamido-pyridine ligands.
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