- Abstract:
-
The synthesis, characterisation and thermal and photochemical reactivity of Ru(CO)2(PPh3)(dppe) 1 towards hydrogen are described. Compound proved to exist in both fac (major) and mer forms in solution. Under thermal conditions, PPh3 is lost from 1 in the major reaction pathway and the known complex Ru(CO)2(dppe)(H)2 2 is formed. Photochemically, CO loss is the dominant process, leading to the alternative dihydride Ru(CO)(PPh3)(dppe)(H)2 3. The major isomer of 3, viz. 3a, contains hydride liga...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/b510616h
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Issue:
- 17
- Pages:
- 2072-2080
- Publication date:
- 2006-05-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:060f4cb9-6a11-4ba1-ba40-80cde7a7c31f
- Source identifiers:
-
12939
- Local pid:
- pubs:12939
- Language:
- English
- Copyright date:
- 2006
Journal article
Contrasting photochemical and thermal reactivity of Ru(CO)2(PPh3)(dppe) towards hydrogen rationalised by parahydrogen NMR and DFT studies.
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