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Journal article

ROTATING-DISK ELECTRODE VOLTAMMETRY - WAVESHAPE ANALYSIS FOR DISP2 AND EC2 PROCESSES

Abstract:

Theory is presented for the shape of current-voltage curves measured at a rotating-disc electrode for the cases where the substrate reacts either via a DISP2 or an EC2 process, and in which the kinetic step is sufficiently fast to allow the use of the reaction layer concept in the mathematical analysis of the problem. It is predicted that if the measured voltammetric waves are analysed using an ordinary Tafel plot (corrected in the usual way for mass transport), then significant curvature wil...

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Publication status:
Published

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Publisher copy:
10.1039/f19888400473
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I More from this journal
Volume:
84
Issue:
2
Pages:
473-482
Publication date:
1988-01-01
DOI:
ISSN:
0300-9599
Language:
English
UUID:
uuid:05c75743-22e0-4381-aabb-e505485d9ffb
Local pid:
pubs:42936
Source identifiers:
42936
Deposit date:
2012-12-19

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