Journal article
Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids.
- Abstract:
-
Csp(2)-Csp(2) cross-coupling reactions between arylboronic acid and aryl halides are widely used in both academia and industry and are strategically important in the development of new agrochemicals and pharmaceuticals. Csp(2)-Csp(3) cross-coupling reactions have been developed, but enantioselective variations are rare and simply retaining the stereochemistry is a problem. Here we report a highly enantioselective Csp(2)-Csp(3) bond-forming method that couples arylboronic acids to racemic ally...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Authors
Funding
Bibliographic Details
- Publisher:
- Nature Publishing Group Publisher's website
- Journal:
- Nature chemistry Journal website
- Volume:
- 7
- Issue:
- 11
- Pages:
- 935-939
- Publication date:
- 2015-11-01
- DOI:
- EISSN:
-
1755-4349
- ISSN:
-
1755-4330
Item Description
- Language:
- English
- Pubs id:
-
pubs:575233
- UUID:
-
uuid:05b74c99-1599-4515-aa4a-e243c0d8c635
- Local pid:
- pubs:575233
- Source identifiers:
-
575233
- Deposit date:
- 2015-11-29
Terms of use
- Copyright holder:
- Macmillan Publishers Limited
- Copyright date:
- 2015
- Notes:
- Copyright © 2015 Macmillan Publishers Limited.
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