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3-azido-3-deoxy-2,2 ': 5,6-di-O-isopropylidene-2-C-hydroxmethyl-D-gulono-1,4-lactone

Abstract:
The crystal structure of azidolactone, C13H19O 6N3, was analyzed. The compound formed by SN2 displacement of the trifluoromethanesulfonate with sodium azide, is the first example of a branched β-sugar amino acid scaffold. The sample was crystallized from diethyl ether by inward diffusion of n-hexane to give lath-shaped colourless crystals. The X-ray crystallographic analysis of the product of the reaction showed the presence of inverted azide.
Publication status:
Published

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Publisher copy:
10.1107/S1600536804029113

Authors


Harding, CC More by this author
Shallard-Brown, H More by this author
Watkin, DJ More by this author
Soengas, R More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume:
60
Issue:
12
Pages:
O2334-O2336
Publication date:
2004-12-05
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
URN:
uuid:05b6071a-8a02-4848-9586-eaf207399a1b
Source identifiers:
39309
Local pid:
pubs:39309
Language:
English

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