- Abstract:
-
Toluene-X van der Waals clusters (where X = Ne, Ne2, Ar, Ar2, Kr, Xe) have been investigated by fluorescence excitation spectroscopy in the region of the S1-S0 transition. With the exception of Xe, for each rare-gas studied, we have assigned cluster transitions in the region of all the strong monomer vibrational bands up to 1000 cm(-1) above the origin band. We have further investigated the S1 relaxation dynamics for each vibrational level of each complex, via their fluorescence decay profile...
Expand abstract - Publisher copy:
- 10.1063/1.1899155
-
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- Journal:
- The Journal of chemical physics
- Volume:
- 122
- Issue:
- 19
- Pages:
- 194315
- Publication date:
- 2005-05-05
- DOI:
- EISSN:
-
1089-7690
- ISSN:
-
0021-9606
- URN:
-
uuid:05a7c2a5-9bc9-42b4-addd-767cd9f789eb
- Source identifiers:
-
58983
- Local pid:
- pubs:58983
- Language:
- English
- Copyright date:
- 2005
Journal article
Electronic spectroscopy of toluene-rare-gas clusters: the external heavy atom effect and vibrational predissociation.
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