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Electronic spectroscopy of toluene-rare-gas clusters: the external heavy atom effect and vibrational predissociation.

Abstract:

Toluene-X van der Waals clusters (where X = Ne, Ne2, Ar, Ar2, Kr, Xe) have been investigated by fluorescence excitation spectroscopy in the region of the S1-S0 transition. With the exception of Xe, for each rare-gas studied, we have assigned cluster transitions in the region of all the strong monomer vibrational bands up to 1000 cm(-1) above the origin band. We have further investigated the S1 relaxation dynamics for each vibrational level of each complex, via their fluorescence decay profile...

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Publisher copy:
10.1063/1.1899155

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The Journal of chemical physics
Volume:
122
Issue:
19
Pages:
194315
Publication date:
2005-05-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:05a7c2a5-9bc9-42b4-addd-767cd9f789eb
Source identifiers:
58983
Local pid:
pubs:58983
Language:
English

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